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SS 2 Catering & Craft Practice

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Menu: Meaning, Scope, Origin, Functions

 

Origin Of The Menu

The menu, initially conceived as a selling aid, had its roots in banquets featuring two courses, each comprising a range of dishes numbering anywhere from 10 to 40. The first set, called “entrée,” was placed on the table before diners arrived, and once consumed, it was replaced by another set known as “relieves or removes.” The term “menu” originated in the 18th century, with the practice of listing meal courses dating back even further. The modern menu emerged in the early 19th century at the Parsan Restaurant of the Palais-Royas, adhering to a classic sequence whose specifics depend on the establishment’s size and class.

 

Meaning And Purpose Of The Menu (Bill Of Fare)

A menu serves as a comprehensive list of available foods and beverages in a catering establishment. Functioning as a selling aid and a means of communication, it informs customers about the offerings and allows them to make personal choices at their convenience.

 

Functions Of The Menu

A food menu plays a vital role in a restaurant:

  1. Communication: Conveys essential information about available items, including descriptions and prices.
  2. Marketing and Promotion: Serves as a powerful marketing tool by showcasing variety and quality, promoting specials, and increasing sales.
  3. Ordering Guide: Assists customers in making informed decisions by organizing options into sections and providing clear descriptions.
  4. Revenue Generation: Contributes significantly to generating revenue through pricing strategies and menu engineering.
  5. Brand Representation: Reflects the restaurant’s brand image through design, layout, and visual elements.
  6. Dietary Guidance: Provides information on dietary requirements, helping customers make suitable choices.
  7. Operational Efficiency: Streamlines kitchen processes, ingredient management, and staff training through clear instructions and standardization.
  8. Innovation and Seasonal Adaptation: Allows for regular updates, introducing new dishes, seasonal items, and limited-time offers.

 

The Classic Sequence Of Menu

 

The classic menu sequence includes various courses:

 

  1. Hors-d’oeuvres: Compound salads, pates, mousses, fruits, seafood, and smoked fish.

  

  1. Soups (Potages): Hot and cold soups.

 

  1. Egg dishes (Oeufs): A variety of egg-based dishes.

 

  1. Pasta and Rice (Farineux): Pasta and rice dishes.

 

  1. Fish (Poisson): Hot and cold fish dishes.

 

  1. Entrée (Main dishes as starters): Small, well-garnished dishes served with rich sauces.

 

  1. Sorbet (Granites): Lightly frozen water ice to refresh the palate.

 

  1. Releve: Main roasts or larger meat joints with potatoes and vegetables.

 

  1. Roast (Roti): Roasted game and poultry dishes.

 

  1. Vegetables (Legumes): Served with roasts or as a separate course.

 

  1. Salad (Salade): Green salads and dressings after the main course.

 

  1. Cold buffet (Buffet froid): Various cold meat, fish, cheese, and egg dishes.

 

  1. Cheese (Fromage): A variety of cheeses with accompaniments.

 

  1. Sweet (Entremets): Hot and cold puddings.

 

  1. Savoury (Savoureux): Sugarless dishes like welsh rarebit or pastry on toast.

 

  1. Fruits (Dessert): Fresh and candied fruits.

 

  1. Beverages: Tea, coffee, milk drinks, etc.

 

Modern menus categorize these courses into starters, main courses, desserts, and beverages. The menu’s scope includes appetizers, main meals, desserts, and beverages, along with variations like continental and ethnic menus.

 

 

 

Factors That Affect Menu Planning

Dining Selection

Menu planning involves the proactive determination of food or dish types to be featured in a meal. This becomes essential when preparing and serving large quantities of food to individuals with diverse tastes and dietary needs. The purpose of menu planning is to meet the nutritional requirements of family members or guests.

 

Benefits of Menu Planning

  1. Menu planning ensures the provision of appealing, nutritious, and visually appealing meals at a reasonable cost to customers.
  2. It prevents food wastage by creatively incorporating leftovers into the next day’s pre-planned menu.
  3. Planned menus help identify underperforming dishes and customer favorites, contributing to strategic business decisions.
  4. It saves time and effort involved in ordering, shopping, and receiving food supplies.
  5. Well-designed menus attract and retain customers, fostering loyalty and potentially drawing in new patrons.
  6. Pre-planned menus with established costs enable quick price quoting for customers.

 

Factors Influencing Menu Planning

Customer preferences are influenced by several factors:

 

  1. Health and Eating Relationship:
  2. Prioritizing a healthy diet over individual “healthy” or “unhealthy” foods.
  3. Growing demand for specific information on cooking methods, such as low-fat and low-salt options.

 

  1. Dietary Requirements: Addressing medical conditions and allergies, with examples like gluten intolerance, diabetes, low cholesterol, and low sodium diets.

 

  1. Cultural and Religious Dietary Influence: Adhering to specific dietary rules based on cultural and religious beliefs, such as abstaining from alcohol, meat on certain days, or following veganism.

 

  1. Vegetarianism: Catering to various forms of vegetarianism, including lacto-ovo vegetarians, lacto vegetarians, strict vegetarians (vegans), semi-vegetarians, and fruitarians.

 

  1. Ethnical Influence: Acknowledging regional or ethnic variations in dishes, recognizing that different groups have unique culinary traditions.

 

Factors to Consider in Menu Planning

  1. Income: The financial resources available influence the type of menu planned.

 

  1. Capability of Kitchen Staff: The proficiency of the kitchen staff affects the variety and complexity of meals that can be prepared.

 

  1. Staff Size/Strength: The number of kitchen staff impacts the menu’s scope and diversity.

 

  1. Equipment of the Kitchen: The availability of labor-saving devices in the kitchen influences the ease and speed of menu preparation.

 

  1. Competition: Awareness of local competition, including pricing and quality, guides the creation of a distinctive menu.

 

  1. Location: Understanding the area and target customer market helps tailor the menu to local preferences.

 

  1. Modern Trends in Food: Balancing traditional and contemporary dishes in response to evolving culinary preferences.

 

  1. Cost Factor: Analyzing costs using modern techniques is crucial for profitability.

 

  1. Availability of Supplies and Reliability of Suppliers: Considering seasonal variations, storage space, and supplier reliability when planning the menu.

 

  1. Foods in Season: Prioritizing seasonal ingredients for cost-effectiveness and freshness.

 

 

 

Types of Menu | Types, Examples, Advantages & Disadvantages

A menu is a compilation of dishes available for serving during a meal and is often used as a selling aid.

 

Menu Types

  1. A LA CARTE (FROM THE CARD)

A la carte refers to cooking dishes to order, with each item individually priced. Customers can choose from a variety of dishes at different prices to create their own menu, which may include one, two, or more courses. True a la carte dishes are prepared upon order, and customers should be prepared for a waiting period.

 

Examples of A La Carte Menu

 

SAMPLE 1

 

Starter

 

  1. Children’s stock soup with 2 slices of bread: $650
  2. Mix vegetable salad, chopped lettuce, tomatoes, green pepper, and cucumber: $550
  3. Green salad crispy lettuce and cucumber in vinaigrette dressing: $750

 

Main Subject

 

  1. Roast fish served with chips/fried and seasoned vegetables: $900
  2. Grilled chicken in chili, served with potatoes or butter rice: $900
  3. OfeNsala, Edikakong, Eforiro, Egusi, or Ogbono prepared with beef, offals, and fish. All soups are served with a choice of Amala, Eba, Pounded yam, or semovita: $850
  4. Jollof rice/white rice/fried rice served with dodo and a choice of chicken

 

Desserts

 

  1. Fruit salads: $450
  2. Queens cake: $200
  3. Vanilla Ice cream: $500
  4. Cream caramel: $450

 

Sommelier recommended wine

  1. Red wine: $100
  2. Renny Martins: $1000

 

SAMPLE 2

 

  1. Cream soup: $500
  2. Tomato soup: $500
  3. Goat meat pepper soup: $2,500
  4. Pepper chicken: $750
  5. Pepper gizzard: $1000
  6. Fresh juice: $800
  7. Juice of the day: $1000
  8. Black currant chapman: $1,500
  9. Irish cream on the rock: $2,500
  10. Red wine on the rock: $2500
  11. Egusi soup and goat meat served with pounded yam: $3000
  12. Eforiro and beef/chicken with semovita: $2,000
  13. Plain yoghurt: $500

 

  1. TABLE D’HOTE (TABLE OF THE HOST)

It is a set menu forming a complete meal at a set price, usually with choices within each course. The term ‘menu du jour’ is sometimes used instead.

 

Example of Table D’hote Menu

 

SAMPLE 1 (N2850 for three-course meal)

 

  1. Cream of vegetable starter
  2. Corn soup, slice of bread starter
  3. Curried crushed potato and a beignet of smoke haddock starter
  4. Semovita served with Okro/Egusi and selected meat stew
  5. Jollof rice, Fried plantain, and Chicken stew main dish
  6. Beef stroganoff, savoury rice, and fried plantain main dish
  7. Tuwoshinkafa, miyankubewa da kaza main dish
  8. Chocolate profiterole sweet
  9. Chocolate Gateay sweet
  10. Vanilla Ice cream sweet
  11. Fruit salad sweet

 

Sommelier recommended wine

  1. Cuvee special (red): $1,000
  2. Mateus Rose: $1,000

 

SAMPLE 2

 

  1. Plain soup
  2. Beef with snow white rice
  3. Irish cream
  4. Fish salad
  5. Plain yoghurt
  6. Champagne: $10,000.00

 

Differences Between A La Carte And Table D’hote

 

A la carte:

 

  1. Guests have a myriad of options—fifteen to twenty tantalizing dishes—presented before them, allowing for a personalized and extensive exploration of culinary delights.

 

  1. The dining setting, devoid of pre-arrangement, acquires structure and sophistication as each patron is served individually, creating a unique and dynamic experience.

 

  1. Each gastronomic masterpiece is meticulously crafted to meet the specific preferences and desires articulated by the discerning guest, ensuring a bespoke dining encounter.

 

  1. The menu unfolds as a detailed narrative, with individual pricing for each culinary creation, affording guests the freedom to select and pay exclusively for their chosen items.

 

  1. Essential elements like rice and potatoes are maintained in a semi-prepared state, requiring final touches before presentation, offering a culinary journey that unfolds with anticipation.

 

Table d’hote:

 

  1. Patrons are presented with a refined selection—three to five carefully curated courses—bestowing a sense of exclusivity and a predetermined gastronomic journey.

 

  1. The dining table, a canvas of elegance, is meticulously set in advance, adorned with a complete ensemble of silverware, creating an immediate ambiance of sophistication.

 

  1. Culinary creations, pre-prepared with precision, sacrifice individual customization for efficiency, promising a seamless and expedited dining experience.

 

  1. The collective pricing strategy embraces all menu items, whether consumed or untouched, providing a streamlined and inclusive approach to the dining expenditure.

 

  1. Ingredients are prepared in advance, eliminating any waiting time, ensuring immediate and gratifying service for patrons seeking a swift and complete dining experience.

 

  1. Carte Du Jour

This is also known as the ‘menu of the day’ or ‘plat du jour,’ combining a la carte, table d’hote, and plat du jour menus.

 

  1. Cyclical Menu

Cyclical menus cover a specific period, such as one month or three months, and consist of set menus for establishments like restaurants, cafeterias, and hospitals. The menu is reused at the end of each period.

 

Advantages Of Cyclical Menu

 

  1. Saves time by eliminating the daily or weekly task of compiling menus.
  2. Efficient use of time and labor.
  3. Reduces the number of commodities held in stock.
  4. Assists in planning storage requirements.

 

Disadvantages Of Cyclical Menu

 

  1. Guests may get bored with the repetition of dishes.
  2. The caterer may miss good buys offered by suppliers on a daily or weekly basis.

 

  1. Tasting Menu

A tasting menu is a set meal with a range of courses, typically between 6 and 10. It is offered in restaurants where the chef provides a sample of the main menu’s dishes. It may include a flight of wine.

 

  1. Hospital Menu

Hospital menus are provided to patients the day before services, allowing them to indicate their preferences. Both National Health Service and private hospitals cater to vegetarians and accommodate religious requirements.

 

  1. Menu for People at Work

Menus for people at work vary based on company policies. They may offer a call order a la carte with items commonly consumed in the area.

 

  1. Menus For Children

Schools emphasize healthy eating and a balanced diet, particularly in boarding schools. Menus may include children’s favorite foods and appropriately sized portions for various cultural and religious backgrounds.

 

  1. Plat Du Jour

Also known as a specialty menu, it can be a set-priced menu or individually priced dishes specializing in the food of a particular country, religion, or a specific dietary requirement. It is usually changed daily and may be more affordable.

 

  1. Special Party or Function Menus

Menus for banquets or functions of all kinds.

 

  1. Others

Include breakfast, tea, dinner, luncheon.

 

 

 

Breakfast Service (Continental & Nigerian)

Breakfast serves as the initial and crucial meal of the day, breaking the overnight fast, and is imperative not to skip. It is advisable for breakfast to be light yet substantial, avoiding oily and heavy foods. The goal is for breakfast to provide sustenance until lunch. In hospitality settings like hotels, breakfast may be served in the hotel restaurant, dining room, a designated breakfast room, or even in the hotel guest’s bedroom or suite.

 

Types of Breakfast

Café complet:

The term “café complet” is commonly used in continental Europe, referring to a continental breakfast with coffee as the primary beverage. Alternatively, the term “the complet” may include tea instead (teacomplet).

 

Café simple or the simple:

“Café simple” or “the simple” entails only a beverage (coffee or tea) without any accompanying food, constituting a minimalist breakfast.

 

Continental Breakfast:

This breakfast variety features dishes from various foreign countries, typically including hot bread items, preserves, juice, and a selection of beverages. The menu has expanded to encompass a broader range, incorporating cheese, assorted bread products, and a variety of beverages.

 

Example of a continental breakfast menu:

  1. Orange juice/apple juice/grapefruit juice
  2. Fried egg/scrambled eggs/poached eggs
  3. Baked beans/mushrooms/tomato
  4. Pork sausage/vegetarian sausage
  5. White toast/dinner roll/Danish pastry/plain bread/croissant
  6. Coffee/decaf coffee/breakfast tea
  7. Skimmed milk/full cream milk
  8. Sugar/honey

 

Full Breakfast:

Also known as English or British breakfast, this meal comprises two to eight courses and typically includes a substantial cooked main course. The extensive menu provides multiple choices for customers.

 

Cover for Full Breakfast:

  1. Napkin
  2. Side plate and side knife
  3. Fish knife and fork
  4. Joint knife and fork
  5. Sweet spoon and fork
  6. Sugar basin and tongs or individual sugar packet in a bowl
  7. Tea strainer
  8. Stands or under plate for tea/coffee pot and hot water jug/hot milk jug.

 

Various items are arranged as part of mise-en-place before the customer is seated, with additional items placed on the table upon seating.

 

Local Breakfast:

This breakfast option comprises two or more courses featuring dishes made from locally grown or processed food common to various ethnic groups.

 

Example of a local breakfast menu

  1. Orange juice/grapefruit juice
  2. Moimoi/akaraballs (beans cake)
  3. Corn/millet porridge/oats
  4. Soya beans milk/skimmed milk/full cream milk
  5. Sugar/honey
  6. Tapioca

 

Examples of Breakfast Menu Items:

  1. Juices: Orange, pineapple, tomato, apple, etc.
  2. Fresh and stewed fruits: Melon, pawpaw, pineapple, mangoes, fruit salad, etc.
  3. Cereals: Corn flakes, weetabix, rice crisps, quaker oats, jollof rice, etc.
  4. Yoghurt: Natural and fruit, regular and low fat
  5. Fish: Fried or grilled fish, smoked fish with poached or scrambled eggs
  6. Eggs: Fried, poached, scrambled, boiled, plain or savory-filled omelet
  7. Meats: Bacon in various styles, various sausages, kidney, steak
  8. Potatoes and vegetables: Hash browns, mushrooms, baked beans, fresh or grilled tomatoes
  9. Pancakes and waffles: Regular pancakes, whole meal pancakes, waffles with toppings, etc.
  10. Cold buffet: Hams, tongue, chicken, smoked cold meat, etc.
  11. Bread items: Toast, rolls, plain sliced white or brown bread, gluten-free bread, doughnut, scones, crisp bread, etc.
  12. Preserves: Jams, marmalade, honey.
  13. Beverages: Tea, coffee (including decaffeinated), chocolate, milk, soy/rice milk, mineral waters.

 

 

 

Luncheon And Dinner

Lunch

Representing the primary meal of the day, lunch is typically consumed in the afternoon as the midday repast. It encompasses a broad range of options, such as plate du jour, carte du jour, continental menu, or local menu. The customary order involves the serving of soup or protein first.

 

Luncheon

This midday meal is specifically designed as part of entertaining guests during a social gathering. It constitutes an afternoon event where a light meal is provided in conjunction with a meeting or other special occasion.

 

For special occasions in our localities, the following dishes are generally well-received:

 

Chicken jollof rice

 

Turkey fried rice

 

Beef coconut rice

 

 

 

Carte Dujour Menu

The term “Carte du jour” translates to “menu of the day.” This concept denotes a distinct menu provided to guests, separate from the regular menu offerings. It amalgamates elements from the à la carte, table d’hôte, and plat du jour menus, each item priced accordingly. This structure allows for individual pricing, as seen in the à la carte menu, or a collective price for the daily special. Essentially, establishments adopting this approach offer flexibility, ensuring patrons have a variety of choices to suit their preferences.

 

À La Carte Lunch Menu Example

 

Starter

  1. Chicken stock soup with two bread slices: N650
  2. Mixed vegetable salad (lettuce, tomatoes, green pepper, cucumber): N550
  3. Green salad with crispy lettuce and cucumber in vinaigrette: N750

 

Main Subject

  1. Roast fish with chips and seasoned vegetables: N900
  2. Grilled chicken in chili with potatoes or buttered rice: N900
  3. Soups like OfeNsala, Edikakong, efo-riro with beef, offal, fish, egusi, or ogbono. Served with options like amala, eba, pounded yam, or semovita: N850
  4. Jollof rice, white rice, fried rice with dodo and chicken: N900

 

Desserts

  1. Fruit salad: N450
  2. Queen’s cake: N200
  3. Vanilla ice cream: N500
  4. Cream caramel: N450

 

Wine Recommendations

  1. Red wine: N100
  2. Remy Martins: N1000

 

À La Carte Menu Featuring Carte Du Jour

  1. Cream soup: N50
  2. Tomato soup: N500
  3. Goat meat pepper soup: N2,500
  4. Pepper chicken: N750
  5. Pepper gizzard: N1,000
  6. Fresh juice: N800
  7. Juice of the day: N1,000
  8. Black currant chapman: N1,500
  9. Irish cream on the rocks: N2,500
  10. Red wine on the rocks: N2,500
  11. Pounded yam with egusi and goat meat: N3,000
  12. Semovita with eforiro beef/chicken: N2,000
  13. Plain yoghurt: N500

 

Daily Special Menu

Chocolate pudding with cream caramel: N1,000

Table D’hôte

  1. Plain soup
  2. Beef with snow white rice
  3. Irish cream
  4. Fish salad
  5. Plain yoghurt
  6. Champagne

 

Price: N10,000.00

 

Daily Special Menu

  1. Roasted Chicken with spaghetti bolognaise
  2. Price: Customizable, starting from N500

 

 

 

Plat Dujour | Hausa Dishes, Igbo Dishes, Yoruba Dishes

This is also known as a speciality menu. It can be a set-priced menu or individually priced menu or individually priced dish specializing in the food of a particular country, religion or a specialized food itself. The speciality could be ethnic, i.e. food on the menu could reflect Chinese, Indian, Igbo, Hausa, Yoruba, Greek, Africa or specialty like diabetic, hypertensive etc. It is usually changed daily and cheaper or better.

In Nigeria, different ethnic groups have their own traditional dishes/ meal. Examples are:

 

Hausa Dishes

  1. Taushe da tu won shinkafa
  2. Karkashi da tuwonshinkafa
  3. Miyan wake da sakwara
  4. Miyanridi da brabisko

 

Igbo Dishes

  1. Offeowerri
  2. Offeujuju
  3. Offeonugbu with fufu
  4. Uziza and utazi

 

Yoruba Dishes

  1. Ewedu soup and amala
  2. Egusi soup with pounded yam
  3. Efoelegusi and eba
  4. Ikokore

 

Foreign Dishes

These are also called civilized dishes. These are dishes that are not naturally taken by the native people. Some of these foreign dishes are:

 

  1. Grilled chicken duchess potatoes
  2. Fish in batter with potatoes
  3. Chicken Marinade with croquettes potatoes
  4. Hamburger American style

 

European Dishes

  1. Fillet steak withYorkshire pudding
  2. Roast chicken with bread sauce
  3. Chicken Marinade with croquettes potatoes
  4. Shepherd’s pie

 

Chinese Dishes

  1. Fried rice with curry stew
  2. Spaghetti with bolognaise sauce

 

Indian Dishes

  1. Curried beef with condiments
  2. Chapatti
  3. Beef shashik
  4. Spaghetti with sauce

 

Japanese Dishes

  1. Chicken sauce chasseur
  2. Beef olives
  3. Mixed grill
  4. Spanish omelets

 

 

 

Coffee Making Service

Coffee is derived from the roasted beans of the coffee tree and is cultivated and shipped from various regions, including South America, India, the Middle East, and the West Indies, such as Sumatra. Brazil holds the title of the world’s largest coffee producer, followed by Colombia in second place, the Ivory Coast in third, and Indonesia in fourth.

 

Guidelines for Bulk Coffee Preparation:

  1. Utilize freshly roasted and ground coffee.
  2. Select the appropriate grind for the specific coffee machine.
  3. Ensure cleanliness of all equipment before use.
  4. Infuse boiling water with coffee, controlling the infusion time based on coffee type and brewing method.
  5. Regulate the temperature, avoiding boiling to prevent a bitter taste.
  6. Strain and serve.
  7. Provide milk (hot or cold), cream, sugar, and alternatives separately.

 

Methods of Bulk Coffee Making and Service:

Dissolving Method (Instant):

    1. Mix soluble coffee solids with boiling water.
    2. Suitable for individual cups or large quantities.

 

Percolation Method:

  1. Utilize an electric percolator with reservoir, strainer, and container.
  2. Add coffee, water, percolate, and serve with optional milk, cream, and sugar.

 

Filtration Method:

  1. Pour boiled water over ground coffee in a container with a fine mesh.
  2. Filter paper may be used to prevent grounds in the cup.
  3. Serve immediately.

 

Vacuum Infusion:

  1. Fill the lower bowl with cold water, add ground coffee, and heat.
  2. Ensure gentle stirring to infuse coffee.
  3. Filter to separate grounds and serve at approximately 82⁰F.

 

Espresso Method:

  1. Italian origin involving steam and pressure.
  2. Provides freshly made cups quickly.
  3. Serve black or as a base for cappuccino.

 

Still Set Method:

  1. Use a central container with filter paper and meshed filter.
  2. Pass boiling water through grounds into urns.
  3. Rinse urns before and after each brew.
  4. Keep coffee and milk separately at correct temperatures for serving.

 

Serving Specialty and Irish Coffee:

  1. Specialty coffee presented on a service salver with necessary equipment.
  2. Irish Coffee made in a Paris goblet with brown sugar, Irish whiskey, and hot coffee.
  3. Stir well, serve on a side plate, and present in front of the customer.

 

 

 

Rate Of Reaction | Meaning, Ways, Rate Curve & Collision Theory

Definition of Reaction Rate

The rate of a chemical reaction is defined as the quantity of reactants converted or products formed per unit time. Typically, it is determined experimentally by measuring the change in concentration of one of the reaction components over time.

 

Methods of Measuring Reaction Rate

Various properties can change with time and be used to measure the rate of reaction, including:

  1. Decrease in mass of the reaction system
  2. Volume of gaseous product
  3. Amount of precipitate formed
  4. Change in color intensity
  5. Change in pH
  6. Change in total gas pressure

 

Features of Rate Curve

The rate curve typically exhibits the following features:

  1. Passes through the origin due to no change in concentration or mass at the start of the reaction.
  2. Initially steep, indicating a fast rate at the beginning.
  3. Becomes less steep later as the rate slows down.
  4. Finally becomes horizontal, signifying that the reaction has reached its endpoint.

 

Rate-related parameters such as average rate of reaction and rate at a particular instant during the reaction can be determined from the rate curve.

 

Collision Theory

The collision theory posits that for a chemical reaction to occur, reactant particles must collide with a certain minimum amount of energy known as activation energy. Effective collisions, those resulting in a chemical reaction, require this minimum energy. Activation energy is the energy barrier that reactants must overcome for the reaction to take place.

 

Factors influencing reaction rate according to the collision theory include:

  1. Energy of the particles
  2. Frequency of collision of the reaction
  3. Activation energy of the reaction

 

Various factors affecting these features can alter the rate of reaction, including the nature of reactants, concentration/pressure (for gases) of reactants, surface area of reactants, temperature of the reaction mixture, presence of light, and the presence of catalysts.

 

Effect of Nature of Reactants

Different substances exhibit different rates of reaction under the same conditions due to their inherent chemical nature. For example, when dilute HCl reacts with zinc, iron, and gold, hydrogen gas is evolved at varying rates.

 

Effect of Concentration of Reactants

Higher concentration results in more frequent collisions among particles, leading to increased effective collisions and a higher rate of reaction. Changes in reactant concentration correspondingly affect the reaction rate.

 

Effect of Surface Area Of Reactants

Involvement of solid reactants introduces the importance of surface area; powdered solids with larger surface areas exhibit higher reaction rates than lumped solids.

 

Effect of Temperature

Increasing temperature increases the reaction rate by supplying energy to reactant particles. This leads to a higher frequency of collisions and more effective collisions, thereby accelerating the reaction. Decreasing temperature has the opposite effect.

 

Effect of Light

Certain reactions are influenced by light intensity, with higher intensity increasing the reaction rate. Photochemical reactions, such as those involving hydrogen and chlorine or the decomposition of hydrogen peroxide, exemplify this dependence on light.

 

Effect of Catalyst

Catalysts influence reaction rates by altering the activation energy without undergoing any permanent change themselves. Positive catalysts lower activation energy, increasing the reaction rate, while negative catalysts or inhibitors increase activation energy, slowing down the reaction.

 

 

Exothermic And Endothermic Reactions

Energy

Energy is defined as the ability to do work. It exists in different forms like: heat, light, sound, electrical, potentials (stored), kinetic etc.

 

Laws of Conservation of Energy

Energy can be changed from one form to another. The total amount of energy before and after the change remains the same. This observation is stated in the law of conservation of energy which states that energy can neither be created nor destroyed but can be changed from one form to another. There are types of energy such as chemical energy, heat energy, and light energy.

 

Heat Content (Enthalpy) of A Substance

Heat content or Enthalpy of a substance is the characteristic internal energy possess by the substance, which is due to the structure and physical state of a substance. The potential energy is due to the structure while the kinetic energy is due to the physical state. Enthalpy of one substance is different from another. Total enthalpy cannot be measured but only enthalpy change. Generally, an enthalpy change (∆H) is the heat that would be exchanged with the surrounding, that is, it is the amount of energy involved in a reaction.

 

Thus,

Enthalpy change = Heat of products – Heat of reactants

 

That is, ∆H = Hproducts – Hreactants

 

The enthalpy change of a given reaction is always written side by side with the given equation and it may be either a positive or negative value.

 

Example: HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l)      ∆H = -57.3kJ

 

Unit of enthalpy change(∆H) is Joules(J) or kilojoules(kJ)

 

Exothermic And Endothermic Reactions

Exothermic Reaction

A chemical reaction in which heat is given off to the surrounding is known as exothermic reaction. When an exothermic reaction occurs, heat is liberated and transferred from the chemicals to the surroundings and the temperature of the reaction mixture rises. The reaction vessel will feel hot.

 

Examples of exothermic reactions include:

 

Reaction between calcium oxide and water

Reaction between an acid and a base.

Combustion of fuel

Corrosion of metals

Respiration

In exothermic reaction, enthalpy change is negative since the heat content of the products is less than the heat content of the reactants.

 

Endothermic Reaction

An Endothermic reaction is a type of reaction in which heat is absorbed from the surroundings. When an endothermic reaction occurs, heat energy is absorbed and transferred from the surrounding to the reactants and the temperature of the reaction mixture falls. The reaction vessel will feel cold.

 

Examples of endothermic reactions are:

Thermal decomposition of calcium trioxocarbonate (IV)

Thermal dissociation of ammonium chloride

Action of light on silver bromide in photographic film

Photosynthesis in plants

In endothermic reaction, the heat content of the product is more than the heat content of the reactant; hence the enthalpy change is positive.

 

Energy Level Diagrams

Energy changes can be presented by diagrams, which shows at once whether reactions are exothermic or endothermic.

 

Heat of Reaction And Chemical Bonds

During chemical reactions, chemical bonds are broken, atoms are regrouped and new bonds are formed. Bond breaking requires energy and bond forming evolves energy. The minimum amount of energy required for bond breaking is called activation energy. While bond breaking is endothermic, bond forming is exothermic. Thus, heat of reaction comes from breaking and forming of chemicals bond. Heat reaction is negative [exothermic] when bond-breaking energy is less than bond forming energy. Heat of reaction is positive [endothermic] when bond-breaking energy is more than bond forming energy.

 

Types of Heat Changes In Chemical Reactions

Heat of Formation

The amount of heat evolved or absorbed when one mole of a substance is formed from its elements is known as heat of formation [or enthalpy of formation].

 

The standard heat of formation of a substance(∆Hfθ) is the heat evolved or absorbed, when one mole of that substance is formed from its elements under standard conditions.

 

For the formation of 1 mole of liquid water, the equation is

 

H2(g)  + 1/2O2(g)® H2O(1)          ∆Hfθ  = – 285kJmol-1

 

Thus, ∆Hfθ of water = – 285kJmol-1

 

Heat of Neutralization

Neutralization is an exothermic reaction. The amount of heat evolved during a neutralization reaction in which one mole of water is formed is known as the heat of neutralization (or enthalpy of neutralization).The standard heat of neutralization ∆Hnθ  is the amount of heat evolved when 1 mole of hydrogen ions, H+, from an acid reacts with 1 mole of hydroxide ions, OH–, from an alkali to form 1 mole of water under standard conditions. Heat of neutralization is also known as heat of formation of one mole of water from its ionic components.

 

H+(aq)  +  OH–(aq)   →  H2O(l)            ∆Hnθ  = – 57.4kJmol-1

 

Heat of Combustion

Combustion reaction is always exothermic. The amount of heat evolved when one mole of a substance is burned completely in oxygen is known as the heat of combustion or enthalpy of combustion. The standard heat of combustion of a substance, ∆HCθ; is the heat evolved when one mole of the substance is burned completely in oxygen under standard conditions.

 

A bomb calorimeter is usually used for accurate determination of heat of combustion.

 

Heat of combustion can be determined from the relation below:

 

Heat of combustion = Heat energy produced   x molar mass

 

Mass burnt                          1

 

When the heat evolved by the burning substance is used to raise the temperature of a known mass of water, then the expression for heat of combustion can be given as:

 

Heat of combustion =  mC∆θ        x  molar mass

 

Mass burnt            1

 

Where m = mass of water

 

C = Specific heat capacity of water

 

∆θ = change in temperature, that is, θ2 – θ1

 

Heat of Solution

Heat of solution can be exothermic or endothermic. Heat of solution is the heat evolved or absorbed when one mole of a substance is dissolved in so much water that further dilution results in no detectable heat change.

 

Standard heat of solution, ∆Hsθ , is the amount of heat evolved or absorbed when 1 mole of substance is dissolved in so much water that further dilution results in no detectable heat change at standard conditions.

 

Heat of combustion

Heat of neutralization

 

Thermodynamics

Thermodynamics is the study of relationship between heat and other forms of energy. System in thermodynamics is any part of the universe chosen for thermodynamics consideration, i.e. the physical and chemical phenomenon or process occurring in a given environment.  A system can be isolated, closed or open. Surrounding is the environment in which a phenomenon or a process occurs.

 

The first law of thermodynamics states that energy can neither be created nor destroyed but may be converted from one form to another.

 

In thermodynamics, heat is represented by q and other forms of energy are referred to as work denoted by w.  The conditions or state of a chemical system is changed when:

 

Heat is evolved or absorbed, and / or

Work is done on or by the system

In any case, the internal energy, U, of the system is affected and it is changed.

 

From first law, heat is changed into internal energy of the system it may be represented by

 

change in internal energy = Heat absorbed by the system + Work done by the system

 

i.e.       U          =          q          +          w

 

Work done by the system is negative since this lead to decrease in internal energy, therefore:

 

U          =          q          –           w

 

For a gaseous system,    w  =  P  V

 

U          =          q         –           P    V

 

U          =          H         –           P    V

 

H          =          U         –           P    V

 

Evaluation

 

State the first law of thermodynamic

Calculate: (a)     the heat adsorbed by a system when it does 72J of work and its internal energy decreases by 90J(b) U for a gas that releases 35J of heat and has 128J of work done on it.

 

Second Law of Thermodynamic

The second law of thermodynamic states that a spontaneous process occurs only if there is an increase in the entropy of a system and its surroundings

 

Factors which determines the spontaneously of a process are:

Enthalpy, H: The heat content of the substances involved

entropy, S: The measure of degree of disorderliness or randomness of a substance free energy G: The energy which is available for doing work.

Entropy (S)

 

Entropy is the measure of degree of disorderliness or randomness of a system. The standard entropy change (∆Sθ) is a state function because it depends on the initial and final state of the system. That is:

 

∆Sθ = Sθproducts – Sθreactants

 

The S.Iunit of is JK-1mol-1

 

Entropy increases from solid to liquid to gaseous state because as you go from solid to liquid to gaseous state, randomness increases, that is; ∆Sθ tends to positive.

 

For a reversible process at constant temperature,

 

S       =          H/T

 

When ∆S is positive, there is increase in entropy.  When ∆S is negative there is decrease in the entropy of a system.

 

 Gibb’s Free Energy

The free energy of a system is the energy which is available for doing work in the system; that is, the driving force that brings about a chemical change.

 

The standard free energy change (∆Gθ) is a state function because it depends on the initial and final state of the system. That is:

 

∆Gθ = Gθproducts – Gθreactants

 

Free energy takes into account the effect of the enthalpy and entropy factors as represented in the equation below:

 

G = H-TS

 

For a change at constant temperature,

 

G =     H – T    S

 

Note:

 

When G is negative, the reaction is spontaneous or feasible.

When G is positive, the reaction is not spontaneous, unless the resultant effect of both      H and    S leads to a net decrease in     G

When    G is zero, the system is in equilibrium

Example: The reaction:  C(s) +  O2(g)                 CO2(g)

 

is carried out at a temperature of 57oC.  If the enthalpy change is -500J and the entropy change is +15J.Calculate the free energy change

 

Solution:

 

G =         H  – T   S

 

=       -5000  – (57 + 273)  x  (+15)

 

=       -5000   – 330 x 15

 

=       -5000   – (+4950)

 

=       -5000   – 4950

 

=       -9950J or -9.950kJ

 

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